Bis{2-[3-(dimethyl­amino)propyl­imino­meth­yl]-4,6-disulfanylphenolato}cobalt(II)

نویسندگان

  • Hai-Yan Li
  • Li-Jun Wang
  • Qiang Wang
  • Qing-Fu Zeng
چکیده

In the title mononuclear complex, [Co(C(12)H(17)N(2)OS(2))(2)], the Co(II) atom is four-coordinated by two N,O-bidentate Schiff base ligands, resulting in a slightly distorted trans-CoN(2)O(2) square-planar coordination.

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منابع مشابه

Bis{2-[2-(dimethyl­amino)ethyl­imino­meth­yl]-4,6-disulfanylphenolato}cobalt(II) monohydrate

In the title hydrated complex, [Co(C(11)H(15)N(2)OS(2))(2)]·H(2)O, the Co(II) atom (site symmetry 2) is coordinated by two O,N,N'-tridentate Schiff base ligands, resulting in a very distorted cis-CoO(2)N(4) octa-hedral geometry for the metal ion. In the crystal, the water mol-ecule (O-atom site symmetry 2) inter-acts with nearby complex mol-ecules by way of bifurcated O-H⋯(O,S) hydrogen bonds.

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Bis{2-[3-(dimethyl­amino)propyl­imino­meth­yl]-4,6-dihydro­seleno­phenolato}zinc(II)

In the title complex, [Zn(C(12)H(17)N(2)OSe(2))(2)], the Zn(II) ion is six-coordinated by two N,N',O-tridentate Schiff base ligands, resulting in a slightly distorted trans-ZnO(2)N(4) octa-hedral coordination for the metal ion.

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Bis{2,4-dichloro-6-[3-(dimethyl­amino)propyl­imino­meth­yl]phenolato}copper(II)

In the title complex, [Cu(C(12)H(15)Cl(2)N(2)O)(2)], the Cu(II) ion is coordinated by one N,O-bidentate and one N,N',O-tridentate Schiff base ligand, resulting in a distorted CuN(3)O(2) square-based pyramidal coordination for the metal ion, with the O atoms lying trans to each other in the basal plane.

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Bis{2-[3-(dimethyl­amino)propyl­imino­meth­yl]-6-methoxy­phenolato-κ3 N,N′,O 1}nickel(II)

The centrosymmetric title complex, [Ni(C(13)H(19)N(2)O(2))(2)], is a mononuclear nickel(II) complex. The Ni(II) atom is coordinated by four N atoms and two O atoms of two deprotonated Schiff base ligands, forming a slightly distorted octa-hedral coordination configuration, in which the tertiary N atoms occupy the axial positions.

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Bis(2-cyclo­hexyl­imino­methyl-4,6-disulfanylphenolato)zinc(II)

In the title complex, [Zn(C(13)H(16)NOS(2))(2)], the Zn(II) ion is four-coordinated by two N,O-bidentate Schiff base ligands, resulting in a distorted trans-ZnN(2)O(2) square-planar geometry for the metal ion.

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عنوان ژورنال:

دوره 65  شماره 

صفحات  -

تاریخ انتشار 2009